Synthesis of new enantiomerically pure organoiodine catalysts and their application in the alpha-functionalization of ketones

Farooq, Umar, Schäfer, Sascha, Shah, Azhar, Freudendahl, Diana Maria and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2010. Synthesis of new enantiomerically pure organoiodine catalysts and their application in the alpha-functionalization of ketones. Synthesis -Stuttgart- (6) , pp. 1023-1029. 10.1055/s-0029-1218640

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Abstract

The synthesis of enantiomerically pure iodoarenes and their application to the α-oxysulfonylation of propiophenone, and the lactonization of 5-oxo-5-phenylpentanoic acid using MCPBA as stoichiometric oxidant are reported to give useful synthetic intermediates in good yields and moderate enantioselectivities.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	hypervalent iodine reagents - organocatalysis - oxidation - stereoselective synthesis
Publisher:	Georg Thieme Verlag
ISSN:	0039-7881
Last Modified:	02 Dec 2022 12:12
URI:	https://orca.cardiff.ac.uk/id/eprint/9789

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