Zhang, Shu Hua, Carter, Emma ORCID: https://orcid.org/0000-0001-6691-2377, Xi, Hong-Wei, Li, Yongxin, Lim, Kok Hwa and So, Cheuk-Wai 2016. Delocalized hypervalent silyl radical supported by amidinate and imino substituents. Inorganic Chemistry 56 (2) , pp. 701-704. 10.1021/acs.inorgchem.6b02427 |
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Official URL: http://dx.doi.org/10.1021/acs.inorgchem.6b02427
Abstract
The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent [LSiSi(Cl){(NtBu)2C(H)Ph}] (1, L = PhC(NtBu)2) with ArN=C=NAr (Ar = 2,6-iPr2C6H3) in toluene afforded the delo-calized hypervalent silyl radical [LSi(-CNAr)2Si{(NtBu)2C(H)Ph}] (2). It possesses a hypervalent silyl radical, which delocalizes throughout the Si2C2 ring.
Item Type: | Article |
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Date Type: | Published Online |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | American Chemical Society |
ISSN: | 0020-1669 |
Date of First Compliant Deposit: | 27 January 2017 |
Date of Acceptance: | 23 December 2016 |
Last Modified: | 06 Nov 2023 23:43 |
URI: | https://orca.cardiff.ac.uk/id/eprint/97829 |
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