Bernechea, Maria ORCID: https://orcid.org/0000-0003-2800-6845, de Jesús, Ernesto, López-Mardomingo, Carmen and Terreros, Pilar 2009. Dendrimer-encapsulated Pd nanoparticles versus palladium acetate as catalytic precursors in the Stille reaction in water. Inorganic Chemistry -American Chemical Society- 48 (10) , pp. 4491-4496. 10.1021/ic9002753 |
Official URL: http://dx.doi.org/10.1021/ic9002753
Abstract
The performance of Pd(OAc)2, Pd0 dendrimer-encapsulated nanoparticles, and PdII-dendrimer complexes in several Stille reactions in water is compared. The presence of the dendrimer suppresses the formation of homocoupling products and allows catalyst recycling. It is suggested that the reaction catalyzed by DENs occurs via palladium species which are leached from the nanoparticle but which remain coordinated to the dendritic macromolecule.
Item Type: | Article |
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Date Type: | Published Online |
Status: | Published |
Schools: | Engineering |
Subjects: | T Technology > TA Engineering (General). Civil engineering (General) |
Publisher: | American Chemical Society |
ISSN: | 0020-1669 |
Date of First Compliant Deposit: | 11 August 2016 |
Last Modified: | 01 Nov 2022 11:04 |
URI: | https://orca.cardiff.ac.uk/id/eprint/93760 |
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