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Strategies for designing supported gold-palladium bimetallic catalysts for the direct synthesis of hydrogen peroxide

Edwards, Jennifer Kelly ORCID: https://orcid.org/0000-0003-4089-2827, Freakley, Simon J., Carley, Albert Frederick, Kiely, Christopher J. ORCID: https://orcid.org/0000-0001-5412-0970 and Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560 2014. Strategies for designing supported gold-palladium bimetallic catalysts for the direct synthesis of hydrogen peroxide. Accounts of Chemical Research 47 (3) , pp. 845-854. 10.1021/ar400177c

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Abstract

Hydrogen peroxide is a widely used chemical but is not very efficient to make in smaller than industrial scale. It is an important commodity chemical used for bleaching, disinfection, and chemical manufacture. At present, manufacturers use an indirect process in which anthraquinones are sequentially hydrogenated and oxidized in a manner that hydrogen and oxygen are never mixed. However, this process is only economic at a very large scale producing a concentrated product. For many years, the identification of a direct process has been a research goal because it could operate at the point of need, producing hydrogen peroxide at the required concentration for its applications. Research on this topic has been ongoing for about 100 years.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0001-4842
Last Modified: 27 Oct 2022 09:33
URI: https://orca.cardiff.ac.uk/id/eprint/66451

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