Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Aryl azide photochemistry in defined protein environments

Morris, Josephine Lydia, Reddington, Samuel C., Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879, Jones, Darran Dafydd ORCID: https://orcid.org/0000-0001-7709-3995, Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595 and Tippmann, Eric Michael 2013. Aryl azide photochemistry in defined protein environments. Organic Letters 15 (4) , pp. 728-731. 10.1021/ol3028779

Full text not available from this repository.

Abstract

A genetically encoded precursor to an aryl nitrene, para-azidophenylalanine, was introduced site specifically into proteins to deduce if distinct environments were capable of caging a reactive organic intermediate. Following photolysis of mutant T4 lysozyme or green fluorescent proteins, EPR spectra showed, respectively, the presence of a triplet nitrene and an anilino radical.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Biosciences
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1523-7060
Funders: EPSRC
Last Modified: 24 Oct 2022 10:42
URI: https://orca.cardiff.ac.uk/id/eprint/45499

Citation Data

Cited 11 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item