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Synthesis of new enantiomerically pure organoiodine catalysts and their application in the alpha-functionalization of ketones

Farooq, Umar, Schäfer, Sascha, Shah, Azhar, Freudendahl, Diana Maria and Wirth, Thomas 2010. Synthesis of new enantiomerically pure organoiodine catalysts and their application in the alpha-functionalization of ketones. Synthesis -Stuttgart- (6) , pp. 1023-1029. 10.1055/s-0029-1218640

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Abstract

The synthesis of enantiomerically pure iodoarenes and their application to the α-oxysulfonylation of propiophenone, and the lactonization of 5-oxo-5-phenylpentanoic acid using MCPBA as stoichiometric oxidant are reported to give useful synthetic intermediates in good yields and moderate enantioselectivities.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: hypervalent iodine reagents - organocatalysis - oxidation - stereoselective synthesis
Publisher: Georg Thieme Verlag
ISSN: 0039-7881
Last Modified: 03 Apr 2018 20:37
URI: http://orca-mwe.cf.ac.uk/id/eprint/9789

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