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Synthesis and substrate-controlled reactions of 2,2′-unsaturated biquinazolinones

Pertusati, Fabrizio, Nutz, Eva, Kariuki, Benson and Coogan, Michael P. 2017. Synthesis and substrate-controlled reactions of 2,2′-unsaturated biquinazolinones. Tetrahedron 73 (1) , pp. 55-63. 10.1016/j.tet.2016.11.060

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Abstract

A series of BiQuinazolinones bearing either double or triple bonds in their lateral chains have been synthesized. These compounds were then subjected to substrate-controlled reactions such as Diels-Alder, epoxidation and Pauson-Khand reactions. The stereoselective outcome observed in these transformations is very promising for the future application of BiQuinazolinones as chiral auxiliaries.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Pharmacy
Subjects: R Medicine > R Medicine (General)
R Medicine > RS Pharmacy and materia medica
Uncontrolled Keywords: BiQuinazolinone; Atropisomers; Diastereoselectivity; Chiral induction
Publisher: Elsevier
ISSN: 0040-4020
Date of First Compliant Deposit: 23 January 2017
Date of Acceptance: 21 November 2016
Last Modified: 08 Dec 2017 10:46
URI: http://orca-mwe.cf.ac.uk/id/eprint/97657

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