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Mixed acetals as new precursors for selenium electrophiles

Uehlin, Lars and Wirth, Thomas 2001. Mixed acetals as new precursors for selenium electrophiles. Phosphorus, Sulfur and Silicon and the Related Elements 171 (1) , pp. 189-194. 10.1080/10426500108046650

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Abstract

A wide range of precursors for selenium electrophiles is already known, but the requirements for the development of polymer-bound selenium reagents are different. Herein we report mixed acetals as new precursor molecules for the synthesis of selenium electophiles under very mild reaction conditions. The use of (MeOCH2Se)2 allows a very fast access to these mixed acetals. Chiral precursor molecules can be synthesized as well and employed in efficient stereoselective selenenylation reactions.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: selenium electrophiles, mixed acetals, stereoselective synthesis
Publisher: Taylor & Francis
ISSN: 1042-6507
Last Modified: 04 Jun 2017 02:08
URI: http://orca-mwe.cf.ac.uk/id/eprint/9761

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