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Inter- versus intramolecular C-H activation: Synthesis and characterization of a novel platinum-carbene complex

Cave, Gareth W. V., Hallett, Andrew Jon, Errington, William and Rourke, Jonathan P. 1998. Inter- versus intramolecular C-H activation: Synthesis and characterization of a novel platinum-carbene complex. Angewandte Chemie -International Edition 37 (23) , pp. 3270-3272. 10.1002/(SICI)1521-3773(19981217)37:23<3270::AID-ANIE3270>3.0.CO;2-2

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Abstract

13C NMR spectroscopy as well as the short bond between the platinum and the C4 atom of the pyridine ring in 1 (1.95 Å) indicate the formation of a novel carbene species. Compound 1 is remarkably stable (m.p. 246°C), probably due to the presence of intramolecular hydrogen bonds, and is formed instead of the expected cyclometalated product. R=n-hexyl.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Carbene complexes; C–H activation; Metalations; N ligands; Platinum
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 19 Mar 2016 22:15
URI: http://orca-mwe.cf.ac.uk/id/eprint/9685

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