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Blue rhenium tricarbonyl DPPZ complexes - low energy charge-transfer absorption at tissue-penetrating wavelengths

Coogan, M. P. and Platts, James Allexis 2016. Blue rhenium tricarbonyl DPPZ complexes - low energy charge-transfer absorption at tissue-penetrating wavelengths. Chemical Communications 52 (84) , pp. 12498-12501. 10.1039/C6CC07125B

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Abstract

fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol−1 cm−1) absorption band between 500–700 nm which are assigned to an n(amido,RNH–) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Advanced Research Computing @ Cardiff (ARCCA)
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 7 October 2016
Date of Acceptance: 28 September 2016
Last Modified: 13 Aug 2019 12:32
URI: http://orca-mwe.cf.ac.uk/id/eprint/95139

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