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Alkynyldiphenylphosphine d8(Pt, Rh, Ir) complexes:  contrasting behavior toward cis-[Pt(C6F5)2(THF)2]

Berenguer, Jesús R., Bernechea, Maria, Forniés, Juan, García, Ana, Lalinde, Elena and Moreno, M. Teresa 2004. Alkynyldiphenylphosphine d8(Pt, Rh, Ir) complexes:  contrasting behavior toward cis-[Pt(C6F5)2(THF)2]. Inorganic Chemistry 43 (25) , pp. 8185-8198. 10.1021/ic048987j

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Abstract

The synthesis and reactivity toward cis-[Pt(C6F5)2(THF)2] of several alkynylphosphine d8 complexes, [Pt(C6F5)(PPh2C⋮CPh)3](CF3SO3), 1, [M(COD)(PPh2C⋮CPh)2](ClO4) (M = Rh, 2, and Ir, 3), and [Pt(o-C6H4E2)(PPh2C⋮CPh)2] (E = O, 6, and S, 7), are reported. Whereas 1 gives rise to the diinserted product 8, which evolves in solution to the bis(diphenylphosphine)naphthalene-based mononuclear complex 9, analogous reactions with 2 or 3 give mixtures of products. The reactions with 6 or 7 afford binuclear heterobridged (μ-κE-o-C6H4E2)/(μ-κP:η2-PPh2C⋮CPh) 11 and 12 or trinuclear (μ3-κ2EE‘-o-C6H4E2)/(μ-κP:η2-PPh2C⋮CPh)2 13 and 14 complexes.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Engineering
Subjects: Q Science > QD Chemistry
T Technology > TA Engineering (General). Civil engineering (General)
Publisher: American Chemical Society
ISSN: 0020-1669
Last Modified: 12 Jun 2019 03:04
URI: http://orca-mwe.cf.ac.uk/id/eprint/93538

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