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An iron-oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase

Tchesnokov, E.P., Faponle, A.S., Quesne, Matthew, Turner, R., Fellner, M., Souness, R.J., Wilbanks, S.M., De visser, S.P and Jameson, G.N.L 2016. An iron-oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase. Chemical Communications- Royal Society of Chemistry 52 (57) , pp. 8814-8817. 10.1039/C6CC03904A

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Abstract

Cysteine dioxygenase is a key enzyme in the breakdown of cysteine, but its mechanism remains controversial. A combination of spectroscopic and computational studies provides the first evidence of a short-lived intermediate in the catalytic cycle. The intermediate decays within 20 ms and has absorption maxima at 500 and 640 nm.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 15 July 2016
Date of Acceptance: 9 June 2016
Last Modified: 05 May 2023 13:01
URI: https://orca.cardiff.ac.uk/id/eprint/92437

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Cited 43 times in Scopus. View in Scopus. Powered By Scopus® Data

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