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Evidence for a surface gold hydride on a nanostructured gold catalyst

Silverwood, I. P., Rogers, S. M., Callear, S. K., Parker, S. F. and Catlow, Charles Richard 2016. Evidence for a surface gold hydride on a nanostructured gold catalyst. Chemical Communications 52 (3) , p. 533. 10.1039/C5CC06118K

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Abstract

Inelastic neutron scattering shows formation of a surface Au–H species, of key importance for the study of catalytic mechanisms. Previous assignment of this feature in the infrared as a purely Ce3+ transition is shown to be erroneous on reducing the catalyst using hydrogen and deuterium.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Funders: EPSRC
Date of First Compliant Deposit: 26 May 2016
Date of Acceptance: 2 November 2015
Last Modified: 04 Jun 2017 09:10
URI: http://orca-mwe.cf.ac.uk/id/eprint/91261

Citation Data

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