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Epoxidation of propene with graphite AuPd-supported nanoparticles

Gupta, Upendra N., Jenkins, Robert Leyshon, Dummer, Nicholas Frank, Bethell, Donald and Hutchings, Graham John 2015. Epoxidation of propene with graphite AuPd-supported nanoparticles. Catalysis Letters 145 (2) , pp. 697-701. 10.1007/s10562-014-1439-6

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Abstract

The oxidation of propene has been studied with O2 as the terminal oxidant using a carbon-supported gold palladium catalyst at 90 °C. The reaction is carried out in acetonitrile as solvent in an autoclave. Propene oxidation is only observed in the presence of benzoyl peroxide acting as a radical initiator, but the presence of O2 is essential to observe oxidation. The addition of aldehydes enhances the formation of the epoxide.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Kluwer
ISSN: 1011-372X
Last Modified: 26 Dec 2017 20:51
URI: http://orca-mwe.cf.ac.uk/id/eprint/87749

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