An investigation of the effect of the addition of tin to %Pd/TiO2 for the hydrogenation of furfuryl alcohol

King, Gavin Morgan, Iqbal, Sarwat, Miedziak, Peter John, Brett, Gemma Louise, Kondrat, Simon A., Yeo, Benjamin Roy, Liu, Xi, Edwards, Jennifer Kelly, Morgan, David John, Knight, David K. and Hutchings, Graham John 2015. An investigation of the effect of the addition of tin to %Pd/TiO2 for the hydrogenation of furfuryl alcohol. ChemCatChem 7 (14) , pp. 2122-2129. 10.1002/cctc.201500242

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Abstract

The selective hydrogenation of furfuryl alcohol was investigated at room temperature by using supported palladium catalysts. The catalysts are very selective to the formation of 2-methylfuran. Furthermore, the addition of tin to palladium showed similar catalytic activity, but was more selective to tetrahydrofurfuryl alcohol. Variation of the Sn/Pd ratio has shown a considerable and interesting effect on the selectivity pattern. Addition of a small amount of Sn (1 wt %) shifted the selectivity towards tetrahydrofurfuryl alcohol and methyltetrahydrofuran, which are ring-saturated molecules. Increasing the tin ratio further decreased the catalytic activity and also showed very poor selectivity to either of these products.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Wiley
ISSN:	1867-3880
Last Modified:	11 Sep 2020 09:15
URI:	http://orca-mwe.cf.ac.uk/id/eprint/87747

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