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Room temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process

O'Malley, Alexander J., Parker, Stewart F., Chutia, Arunabhiram, Farrow, Matthew R., Silverwood, Ian P., García-Sakai, Victoria and Catlow, Charles Richard 2016. Room temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process. Chemical Communications 52 (14) , pp. 2897-2900. 10.1039/C5CC08956E

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Abstract

Neutron scattering methods observed complete room temperature conversion of methanol to framework methoxy in a commercial sample of methanol-to-hydrocarbons (MTH) catalyst H-ZSM-5, evidenced by methanol immobility and vibrational spectra matched by ab initio calculations. No methoxylation was observed in a commercial HY sample, attributed to the dealumination involved in high silica HY synthesis.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Date of First Compliant Deposit: 30 March 2016
Date of Acceptance: 7 December 2015
Last Modified: 16 May 2019 13:11
URI: http://orca-mwe.cf.ac.uk/id/eprint/87725

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