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Probing the excited states of d(6) metal complexes containing the 2,2 '-bipyrimidine ligand using time-resolved infrared spectroscopy. 1. Mononuclear and homodinuclear systems

Alsindi, Wassim Z., Easun, Timothy, Sun, X.-Z., Ronayne, Kate L., Towrie, Michael, Herrera, Juan-Manuel, George, Michael W. and Ward, Michael D. 2007. Probing the excited states of d(6) metal complexes containing the 2,2 '-bipyrimidine ligand using time-resolved infrared spectroscopy. 1. Mononuclear and homodinuclear systems. Inorganic Chemistry 46 (9) , pp. 3696-3704. 10.1021/ic0623112

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Abstract

Picosecond-time-scale time-resolved infrared spectroscopic studies on a range of mononuclear and dinuclear complexes containing {Re(CO)3Cl}, {Ru(bipy)(CN)4}2-, and {Ru(bpyam)2}2+ units [bipy = bypyridine; bpyam = 2,2‘-bipyridine-4,4‘-(CONEt2)2] connected to one or both of the binding sites of 2,2‘-bipyrimidine have provided information on the electronic structure and dynamics of triplet metal-to-ligand charge-transfer (MLCT) excited states of dinuclear complexes in the {Re(CO)3Cl} and {Ru(bipy)(CN)4}2- complexes (see figure) and fast interconversion between different MLCT states in the {Ru(bpyam)2}2+ complexes.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0020-1669
Last Modified: 04 Jun 2017 07:58
URI: http://orca-mwe.cf.ac.uk/id/eprint/71027

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