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Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-3N,N',N''}nickel(II) dichloride 3.5-hydrate

Kariuki, Benson and Al-Sudani, Abdul-Razak H. 2014. Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-3N,N',N''}nickel(II) dichloride 3.5-hydrate. Acta Crystallographica Section E - Structure Reports Online 70 (9) , m339-m340. 10.1107/S1600536814019035

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Abstract

In the title compound, [Ni(C13H17N3)2]Cl2·3.5H2O, the geom­etry of the NiN6 complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol­ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol­ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O-HO, O-HCl and N-HCl hydrogen-bonding inter­actions form a three-dimensional network structure.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: International Union of Crystallography
ISSN: 1600-5368
Last Modified: 18 Feb 2019 15:37
URI: http://orca-mwe.cf.ac.uk/id/eprint/66122

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