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Triptycene-based organic molecules of intrinsic microporosity

Taylor, Rupert, Carta, Mariolino, Bezzu, C. Grazia, Walker, Jonathan, Msayib, Kadhum J., Kariuki, Benson and McKeown, Neil B. 2014. Triptycene-based organic molecules of intrinsic microporosity. Organic Letters 16 (7) , pp. 1848-1851. 10.1021/ol500591q

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Abstract

Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demonstrated by apparent BET surface areas in the range of 515–702 m2 g–1. Bulky cyclic 1′,2′,3′,4′-tetrahydro-1′,1′,4′,4′-tetramethylbenzo units placed on the triptycene termini are especially efficient at enhancing microporosity.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1523-7060
Last Modified: 04 Jun 2019 12:58
URI: http://orca-mwe.cf.ac.uk/id/eprint/66119

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