Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Rapid electrochemical deprotection of the isonicotinyloxycarbonyl group from carbonates and thiocarbonates in a microfluidic reactor

Arai, Kenta and Wirth, Thomas 2014. Rapid electrochemical deprotection of the isonicotinyloxycarbonyl group from carbonates and thiocarbonates in a microfluidic reactor. Organic Process Research and Development , 140708073813000. 10.1021/op500155f

Full text not available from this repository.

Abstract

Electroreductive deprotection of the isonicotinyloxycarbonyl (iNoc) group from hydroxy, thiol, and amino groups was carried out in an electrochemical microreactor. The small distance of the platinum electrodes in the microreactor enables a rapid electrochemical redox reaction without added electrolytes. As a result, the electrochemical deprotection of O- and S-iNoc aromatic substrates was achieved in short reaction times (<2 min), while N-iNoc and nonaromatic substrates did not react under the same reaction conditions. This method enables a rapid and site-selective deprotection of O- or S-iNoc groups without removal of N-iNoc moieties.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1083-6160
Last Modified: 18 Feb 2019 13:27
URI: http://orca-mwe.cf.ac.uk/id/eprint/63620

Citation Data

Cited 3 times in Google Scholar. View in Google Scholar

Cited 23 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item