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Enantioselective diamination with novel chiral hypervalent iodine catalysts

Mizar, Pushpak, Laverny, Aragorn, El-Sherbini, Mohammad, Farid, Umar, Brown, Michael, Malmedy, Florence and Wirth, Thomas 2014. Enantioselective diamination with novel chiral hypervalent iodine catalysts. Chemistry - A European Journal 20 (32) , pp. 9910-9913. 10.1002/chem.201403891

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Abstract

Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal-free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Cyclization; diamination; hypervalent iodine; organocatalysis; stereoselective synthesis.
Publisher: Wiley
ISSN: 0947-6539
Last Modified: 24 Sep 2020 16:30
URI: http://orca-mwe.cf.ac.uk/id/eprint/63619

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