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Enantioselective diamination with novel chiral hypervalent iodine catalysts

Mizar, Pushpak, Laverny, Aragorn, Elsherbini, Mohamed, Farid, Umar, Brown, Michael, Malmedy, Florence and Wirth, Thomas 2014. Enantioselective diamination with novel chiral hypervalent iodine catalysts. Chemistry - A European Journal 20 (32) , pp. 9910-9913. 10.1002/chem.201403891

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Abstract

Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal-free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Cyclization; diamination; hypervalent iodine; organocatalysis; stereoselective synthesis.
Publisher: Wiley
ISSN: 0947-6539
Last Modified: 07 Feb 2020 15:45
URI: http://orca-mwe.cf.ac.uk/id/eprint/63619

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