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Rearrangement of epoxides to allylic alcohols in the presence of reusable basic resins

Smith, Keith, El-Hiti, Gamal A., Matthews, Ian, Al-Shamali, Mahmoud and Watson, Trystan 2009. Rearrangement of epoxides to allylic alcohols in the presence of reusable basic resins. Catalysis Letters 128 (1-2) , pp. 101-105. 10.1007/s10562-008-9705-0

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Abstract

We have modified Merrifield’s resin to provide polymers containing secondary amine groups. Lithiation of the solids gives strongly basic yet poorly nucleophilic resins useful for rearrangement of epoxides to their corresponding allylic alcohols. The resins are easy to handle, non-volatile, non-toxic, and are easily recovered and reused, providing environmental and economic benefits that might have commercial viability.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Epoxide ; Modified basic Merrifield’s resin ; Rearrangement ; Allylic alcohols ; Heterogeneous reactions
Publisher: Springer Verlag
ISSN: 1011-372X
Date of First Compliant Deposit: 30 March 2016
Last Modified: 04 Jun 2017 01:56
URI: http://orca-mwe.cf.ac.uk/id/eprint/6124

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