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Lessons on the Discovery and Assignment of Polymorphs, Highlighted by the Case of the Latent Pigment DPP-Boc

MacLean, E. J., Tremayne, M., Kariuki, Benson, Cameron, J. R. A., Roberts, M. A. and Harris, Kenneth David Maclean 2009. Lessons on the Discovery and Assignment of Polymorphs, Highlighted by the Case of the Latent Pigment DPP-Boc. Crystal Growth & Design 9 (2) , pp. 853-857. 10.1021/cg800466x

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Abstract

The latent pigment 1,4-diketo-2,5-di-t-butoxycarbonyl-3,6-diphenylpyrrolo[3,4-c]pyrrole (DPP-Boc) has three well-characterized polymorphic forms (denoted α, β, and γ) in the solid state, although some confusion exists in the literature concerning the assignment of these polymorphs. This paper clarifies the assignment of the three polymorphs of DPP-Boc, discusses various issues concerning the polymorphism of this material, and highlights several general issues regarding the characterization, discovery, and assignment of polymorphic systems.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 1528-7483
Last Modified: 04 Jun 2017 01:55
URI: http://orca-mwe.cf.ac.uk/id/eprint/6055

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