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2,7-Di-tert-butylnaphtho[1,8-cd][1,2]dithiole 1,2-dioxides: thermally stable, photochemically active vic-disulfoxides

Grainger, Richard S., Patel, Bhaven and Kariuki, Benson 2009. 2,7-Di-tert-butylnaphtho[1,8-cd][1,2]dithiole 1,2-dioxides: thermally stable, photochemically active vic-disulfoxides. Angewandte Chemie 48 (26) , pp. 4832-4835. 10.1002/anie.200901788

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Abstract

Bulking up: The thermal barrier to rearrangement of a vic-disulfoxide is significantly increased through steric buttressing about the (O)SS(O) bond. Whereas the title compounds represent the most thermally stable vic-disulfoxides known to date, they also undergo a novel photomediated epimerization at room temperature

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 1433-7851
Last Modified: 18 May 2019 09:38
URI: http://orca-mwe.cf.ac.uk/id/eprint/5958

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