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A rhenium tricarbonyl 4'-oxo-terpy trimer as a luminescent molecular vessel with a removable silver stopper

Coogan, Michael Peter, Fernandez-Moreira, Vanesa, Kariuki, Benson, Pope, Simon J. A. and Thorp-Greenwood, Flora Lottie 2009. A rhenium tricarbonyl 4'-oxo-terpy trimer as a luminescent molecular vessel with a removable silver stopper. Angewandte Chemie - International Edition 48 (27) , pp. 4965-4968. 10.1002/anie.200900981

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Abstract

Shining metal cups: A luminescent tube of triangular cross-section and stoppered by a silver ion (see picture: Re yellow, N blue, O red) is formed in two steps from commercial materials. The silver ion can be removed to give a tube, and both species are potential hosts for small ions and molecules; a change in luminescence is triggered by the encapsulation of silver.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Uncontrolled Keywords: Host–guest chemistry ; Luminescence ; Metallacycles ; Molecular vessels ; Rhenium
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 04 Jun 2017 01:54
URI: http://orca-mwe.cf.ac.uk/id/eprint/5896

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