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Cover Picture: Catalytic and mechanistic insights of the low-temperature selective oxidation of methane over Cu-promoted Fe-ZSM-5 (Chem. Eur. J. 49/2012)

Hammond, Ceri, Jenkins, Robert Leyshon, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Ab Rahim, Mohd Hasbi, Forde, Michael M., Thetford, Adam, Murphy, Damien Martin, Hagen, Henk, Stangland, Eric E., Moulijn, Jacob, Taylor, Stuart Hamilton, Willock, David James and Hutchings, Graham John 2012. Cover Picture: Catalytic and mechanistic insights of the low-temperature selective oxidation of methane over Cu-promoted Fe-ZSM-5 (Chem. Eur. J. 49/2012). Chemistry - A European Journal 18 (49) , p. 15557. 10.1002/chem.201290208

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Abstract

Methane to methanol conversion presents one of the most challenging targets in catalysis. Recently, it was demonstrated that an iron- and copper-containing MFI-type zeolite is able to catalytically convert methane to methanol in an aqueous solvent at selectivities above 90 % by using H2O2 as the terminal oxidant. To facilitate understanding of the precise roles of the catalyst and the full mechanistic cycle, C. Hammond, G. J. Hutchings et al. present an in-depth study of the kinetic parameters and mechanistic features of this system in their Full Paper on page 15735 ff. The catalytic system in question results in a low-energy methane activation route, and allows selective C1-oxidation to occur under mild reaction conditions

Item Type: Article
Date Type: Publication
Status: Published
Schools: Advanced Research Computing @ Cardiff (ARCCA)
Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: catalysis; gas; heterogeneous catalysis; methane; oxidation; zeolites
ISSN: 09476539
Last Modified: 16 Jun 2019 00:04
URI: http://orca-mwe.cf.ac.uk/id/eprint/57550

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