Mania, Philipp, Verel, Rene, Jenny, Florian, Hammond, Ceri ORCID: https://orcid.org/0000-0002-9168-7674 and Hermans, Ive 2013. Thermal restructuring of silica-grafted TiClx species and consequences for epoxidation catalysis. Chemistry - a European Journal 19 (30) , pp. 9849-9858. 10.1002/chem.201300842 |
Official URL: http://dx.doi.org/10.1002/chem.201300842
Abstract
Anchoring titanium: Grafting of TiCl4 to site-isolated silanol groups on silica initially leads to freely rotating species. Upon heating, a thermal restructuring takes place, causing the elimination of TiCl4 and the formation of more strongly anchored titanium species, which were found to be highly active and stable epoxidation catalysts.
Item Type: | Article |
---|---|
Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | heterogeneous catalysis; epoxidation; NMR spectroscopy; structure–activity relationships; titanium |
Publisher: | Wiley Blackwell |
ISSN: | 0947-6539 |
Last Modified: | 25 Oct 2022 09:10 |
URI: | https://orca.cardiff.ac.uk/id/eprint/57523 |
Citation Data
Cited 24 times in Scopus. View in Scopus. Powered By Scopus® Data
Actions (repository staff only)
Edit Item |