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Systematic study of the oxidation of methane using supported gold palladium nanoparticles under mild aqueous conditions

Ab Rahim, Mohd Hasbi, Forde, Michael M., Hammond, Ceri, Jenkins, Robert Leyshon, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Carley, Albert Frederick, Taylor, Stuart Hamilton, Willock, David James and Hutchings, Graham John 2013. Systematic study of the oxidation of methane using supported gold palladium nanoparticles under mild aqueous conditions. Topics in Catalysis 56 (18-20) , pp. 1843-1857. 10.1007/s11244-013-0121-3

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Abstract

The oxidation of methane using hydrogen peroxide has been studied using supported gold palladium catalysts prepared using the incipient wetness technique. The effect of reaction conditions and catalyst parameters has been investigated. The supported gold palladium nanoparticles produce methyl hydroperoxide as the primary reaction product which is subsequently converted to methanol with high selectivity, ca. 40–70 %. The selectivity to methanol is influenced by the oxidation state the palladium component of the catalyst. In contrast to homogeneous gold and palladium catalysts the heterogeneous gold palladium nanoalloys are reusable and affords high oxygenate selectivity (ca. 90 %).

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Gold; Palladium; Methane; Oxidation; Nanoalloy; Methanol; Methylhydroperoxide
Publisher: Springer
ISSN: 1022-5528
Funders: Dow Chemical Company
Last Modified: 14 Apr 2019 22:06
URI: http://orca-mwe.cf.ac.uk/id/eprint/53341

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