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Rationalization of interactions in precious metal/ceria catalysts using the d-band center model

Acerbi, N., Edman Tsang, S. C., Jones, G., Golunski, Stanislaw E. and Collier, P. 2013. Rationalization of interactions in precious metal/ceria catalysts using the d-band center model. Angewandte Chemie - International Edition 52 (30) , pp. 7737-7741. 10.1002/anie.201300130

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Abstract

A correlation between ceria reducibility and precious metal d-band center is reported for ceria-supported precious metal catalysts. The results could provide the missing link to fully explain the occurrence of strong metal–support interaction (SMSI) and hydrogen spillover in catalysts that consist of dispersed metals in contact with reducible metal oxides.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: ceria; d-band center; electronic effect; redox chemistry; supported catalysts
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 04 Jun 2017 05:05
URI: http://orca-mwe.cf.ac.uk/id/eprint/48198

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