Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Stereoselective synthesis of 2-dienyl-substituted pyrrolidines using an eta(4)-dienetricarbonyliron complex as the stereodirecting element: Elaboration to the pyrrolizidine skeleton

Williams, I., Kariuki, Benson, Reeves, K. and Cox, Liam R. 2006. Stereoselective synthesis of 2-dienyl-substituted pyrrolidines using an eta(4)-dienetricarbonyliron complex as the stereodirecting element: Elaboration to the pyrrolizidine skeleton. Organic Letters 8 (20) , pp. 4389-4392. 10.1021/ol061132l

Full text not available from this repository.

Abstract

Primary amines react with keto-aldehyde functionality located in the side-chain of an η4-dienetricarbonyliron complex to provide the corresponding pyrrolidines in excellent diastereoselectivity. Two of the pyrrolidine products, 1i and 1k, have been elaborated into pyrrolizidines using a 1,5-C−H insertion and radical cyclization strategy, respectively.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 1523-7060
Last Modified: 04 Jun 2017 04:59
URI: http://orca-mwe.cf.ac.uk/id/eprint/47240

Citation Data

Cited 14 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item