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In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals

Bezzu, Caterina Grazia, Kariuki, Benson, Helliwell, Madeleine, Tuna, Floriana, Warren, John E., Allan, David R. and McKeown, Neil B. 2013. In-situ coordination chemistry within cobalt-containing phthalocyanine nanoporous crystals. CrystEngComm 15 (8) , pp. 1545-1550. 10.1039/c2ce26463c

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Abstract

Nanoporous crystals formed by the cobalt complex of 2,3,9,10,16,17,23,24-octa(2′,6′-di-iso-propyphenoxy)phthalocyanine were used to demonstrate in situ coordination chemistry by single-crystal-to-single-crystal transformations. Ligand exchange, including the introduction of imidazole with the apparent simultaneous oxidation of the metal centre, was readily achieved by simply adding the new ligand into the solvent in contact with the Phthalocyanine nanoporous crystals (PNCs). In addition, chloride and bromide axial ligands were introduced by the use of aqueous hydrochloric, hydrobromic acid or bromine as reagents.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1466-8033
Last Modified: 14 Apr 2018 19:46
URI: http://orca-mwe.cf.ac.uk/id/eprint/47160

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