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Highly stereoselective metal-free oxyaminations using chiral hypervalent iodine reagents

Farid, Umar and Wirth, Thomas 2012. Highly stereoselective metal-free oxyaminations using chiral hypervalent iodine reagents. Angewandte Chemie. International Edition 51 (14) , pp. 3462-3465. 10.1002/anie.201107703

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Abstract

The ring and I: Hypervalent iodine compounds avoid the issues of toxicity or complicated ligands of many transition-metal-based systems. A highly enantioselective oxyamination of alkenes with N-sulfonyl ureas employing chiral, lactic acid-based hypervalent iodine reagents gives a facile synthesis of enantiomerically pure 2-arylproline derivatives (see scheme) for the first time.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Amino alcohols; Aminohydroxylation; Cyclization; Hypervalent iodine; Stereoselective synthesis
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 04 Jun 2017 03:48
URI: http://orca-mwe.cf.ac.uk/id/eprint/26908

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