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Structural rationalization of the phase transition behavior in a solid organic inclusion compound: bromocyclohexane/thiourea

Palmer, Benjamin A., Kariuki, Benson, Morte-Ródenas, Anabel and Harris, Kenneth Kenneth David Maclean 2012. Structural rationalization of the phase transition behavior in a solid organic inclusion compound: bromocyclohexane/thiourea. Crystal Growth and Design 12 (2) , pp. 577-582. 10.1021/cg201656y

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Abstract

Structural properties of the bromocyclohexane/thiourea inclusion compound have been determined using both single-crystal and powder X-ray diffraction over a range of temperatures above and below a first-order phase transition at 233 K in this material. The results demonstrate marked contrasts to the phase transition behavior in the prototypical cyclohexane/thiourea inclusion compound, demonstrating that relatively small changes in molecular geometry (in this case bromine substitution) can have a profound influence on the structural properties of the low-temperature phase in such materials

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 15287483
Last Modified: 18 May 2019 09:38
URI: http://orca-mwe.cf.ac.uk/id/eprint/26417

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