Saiman, Mohd Izham, Brett, Gemma Louise, Tiruvalam, Ramchandra, Forde, Michael M., Sharples, Katherine Mary, Thetford, Adam, Jenkins, Robert Leyshon, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Murphy, Damien Martin, Bethell, Donald, Willock, David James, Taylor, Stuart Hamilton, Knight, David Wiliam, Kiely, Christopher John and Hutchings, Graham John 2012. Involvement of surface-bound radicals in the oxidation of toluene using supported Au-Pd nanoparticles. Angewandte Chemie. International Edition 51 (24) , pp. 5981-5985. 10.1002/anie.201201059 |
Official URL: http://dx.doi.org/10.1002/anie.201201059
Abstract
Au-Pd nanoparticles having a mean particle size of 3–4 nm and supported on titania (see figure; scale bar 2 nm) exhibit high activity in the selective oxidation of aromatic hydrocarbons using tert-butyl hydroperoxide as an oxidant. The supported nanoparticles stabilize surface-bound radicals.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Cardiff Catalysis Institute (CCI) Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | alloys; gold; heterogeneous catalysis; nanoparticles; palladium |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Funders: | Dow Chemical Company |
Last Modified: | 06 Jun 2020 15:33 |
URI: | http://orca-mwe.cf.ac.uk/id/eprint/23662 |
Citation Data
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