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Large thermoelectric figure of merit at high temperature in Czochralski-grown clathrate Ba8Ga16Ge30

Rowe, David Michael, Muller, E, Palmquist, A E and Platzek, D 2006. Large thermoelectric figure of merit at high temperature in Czochralski-grown clathrate Ba8Ga16Ge30. Journal of Applied Physics 99 (2) , 023708. 10.1063/1.2163979

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Abstract

The Czochralski method was used to grow a 46-mm-long crystal of the Ba8Ga16Ge30 clathrate, which was cut into disks that were evaluated for thermoelectric performance. The Seebeck coefficient and electrical and thermal conductivities all showed evidence of a transition from extrinsic to intrinsic behavior in the range of 600–900 K. The corresponding figure of merit (ZT) was found to be a record high of 1.35 at 900 K and with an extrapolated maximum of 1.63 at 1100 K. This makes the Ba8Ga16Ge30 clathrate an exceptionally strong candidate for medium and high-temperature thermoelectric applications.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Engineering
Uncontrolled Keywords: thermoelectric power, Seebeck effect, electrical conductivity, thermal conductivity, barium alloys, gallium alloys, germanium alloys
Additional Information: ------- Publisher's copyright requirements "Copyright (2004) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Tian, Y and Li, G and Shinar, J and Wang, N. L. and Cook, B A and Anderegg, J. W. and Constant, A. P. and Russell, A M and Snyder, John Evan (2004) Electrical transport in amorphous semiconducting AlMgB14 films. Applied Physics Letters , 85 (7). pp. 1181-1183. ISSN 10773118 (10.1063/1.1781738)and may be found at http://apl.aip.org/resource/1/applab/v85/i7/p1181_s1."
Publisher: American Institute of Physics
ISSN: 1089-7550
Last Modified: 06 May 2023 09:59
URI: https://orca.cardiff.ac.uk/id/eprint/1931

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