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Homonuclear two-dimensional J-resolved spectroscopy. The examination of resonances due to strong coupling in the two-dimensional J-spectrum of 1,6-diazathianthrene: The role of first order character in the position and intensity of resonances due to strong coupling. [Chemistry of the phenoxathiins and isosterically related heterocycles. Part 26]

Puig-Torres, Salvador, Gampe, Robert T., Martin, Gary E., Willcott, M. Robert and Smith, Keith 1983. Homonuclear two-dimensional J-resolved spectroscopy. The examination of resonances due to strong coupling in the two-dimensional J-spectrum of 1,6-diazathianthrene: The role of first order character in the position and intensity of resonances due to strong coupling. [Chemistry of the phenoxathiins and isosterically related heterocycles. Part 26]. Journal of Heterocyclic chemistry 20 (1) , pp. 253-256. 10.1002/jhet.5570200157

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Abstract

Resonances due to strong coupling were observed in the two-dimensional J-resolved (2DJ) 1H-nmr spectrum of 1,6-diazathianthrene. Complete analysis of the 2DJ spectral responses predicts that the resonances due to strong coupling are shifted outward from F1 = 0 Hz with a corresponding diminution in intensity as the term vA- vB increases in proceeding to successively higher spectrometer operating frequencies.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Additional Information: This paper represents part XXVI in the series, “Chemistry of the Phenoxathiins and Isosterically Related Heterocycles”. For the previous paper in this series, see: S. Puig-Torres, C. H. Womack, G. E. Martin and K. Smith, J. Heterocyclic Chem., 19, 1561(1982). This work was abstracted, in part, from the M. S. in Pharmacy Thesis of S. P.-T., University of Houston, January, 1982.
Publisher: Wiley
ISSN: 0022-152x
Last Modified: 04 Jun 2017 02:57
URI: http://orca-mwe.cf.ac.uk/id/eprint/14528

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