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Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex

Smith, Keith and Liu, Chia-Hui 2002. Asymmetric epoxidation using a singly-bound supported Katsuki-type (salen)Mn complex. Chemical Communications (8) , pp. 886-887. 10.1039/b200246a

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Abstract

We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a single hydroxyalkyl group at its 6-position, and also its Mn(III) complex; attachment of the complex to a polymer gives a highly enantioselective and recoverable catalyst for epoxidation of 1,2-dihydronaphthalene.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Date of First Compliant Deposit: 30 March 2016
Last Modified: 19 May 2023 03:31
URI: https://orca.cardiff.ac.uk/id/eprint/14259

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