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{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)

Rehbein, Julia, Schürmann, M., Preut, H. and Hiersemann, M. 2009. {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate). Acta Crystallographica Section E - Structure Reports Online E65 (7) , M737. 10.1107/S1600536809020364

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Abstract

In the title compound, [Cu(C17H30N2O2)(C3H7NO)2][SbF6]2, which is a potential catalyst in the asymmetric Gosteli-Claisen rearrangement, the Cu atom adopts a distorted cis-CuN2O2 square-planar geometry arising from N,N'-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C-HO contacts occur within the ligand and two weak intermolecular C-HF bonds may help to establish the packing.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: International Union of Crystallography
ISSN: 1600-5368
Last Modified: 19 Mar 2016 22:21
URI: http://orca-mwe.cf.ac.uk/id/eprint/13005

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