Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Carbonylation of doubly lithiated n-pivaloylanilines. A novel approach to dioxindoles via intramolecular trapping of aromatic acyllithiums

Smith, Keith and Pritchard, Gareth J. 1990. Carbonylation of doubly lithiated n-pivaloylanilines. A novel approach to dioxindoles via intramolecular trapping of aromatic acyllithiums. Angewandte Chemie - International Edition 29 (3) , pp. 282-283. 10.1002/anie.199002821

Full text not available from this repository.

Abstract

A novel entry to indole derivatives 3 is provided by the title reaction. The hitherto greatly restricted possibilities of using the carbonylation of organolithium compounds in syntheses are extended considerably. The double lithiation of 1, carbonylation of the intermediates at room temperature, and subsequent protonation furnishes the compounds 2, which can be readily converted into 3.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 04 Jun 2017 02:50
URI: http://orca-mwe.cf.ac.uk/id/eprint/12652

Citation Data

Cited 33 times in Google Scholar. View in Google Scholar

Cited 33 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item