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A general route to synthesize supported isolated oxide and mixed-oxide nanoclusters at sizes below 5 nm

Bonne, Magali, Sellam, Djamila, Dacquin, Jean-Philippe, Lee, Adam Fraser, Wilson, Karen, Olivi, Luca, Cognigni, Andrea, Marécot, Patrice, Royer, Sébastien and Duprez, Daniel 2011. A general route to synthesize supported isolated oxide and mixed-oxide nanoclusters at sizes below 5 nm. Chemical Communications 47 (5) , pp. 1509-1511. 10.1039/c0cc02662j

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Abstract

A simple and efficient route to prepare supported nanocrystalline oxides is presented. The synthesis procedure, i.e. in situ autocombustion of a glycine complex, allows the production of nanocrystals in a porous matrix presenting larger pore size. An example of successful formation of 2–5 nm nanocrystals is given for a single oxide (Fe2O3), a mixed-oxide structure (LaCoO3 perovskite-type) and a nickel-doped oxide.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Last Modified: 19 Mar 2016 22:20
URI: http://orca-mwe.cf.ac.uk/id/eprint/12616

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