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Structurally defined α-Tetralol-Based chiral hypervalent iodine reagents

Hokamp, Tobias and Wirth, Thomas 2019. Structurally defined α-Tetralol-Based chiral hypervalent iodine reagents. Journal of Organic Chemistry 84 (13) , pp. 8674-8682. 10.1021/acs.joc.9b01315
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Abstract

A novel class of chiral hypervalent iodine reagents containing an α-tetralol-scaffold is being introduced. Iodine triacetate is employed in a key-step as highly selective and efficient iodinating reagent for a short and convenient synthesis of iodine(III) derivatives. Solid state X-ray analyses offer valuable structural information while reactivities and stereoselectivities are investigated in three model reactions.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 0022-3263
Funders: Fonds der Chemischen Industrie
Date of First Compliant Deposit: 19 June 2019
Date of Acceptance: 9 June 2019
Last Modified: 19 Oct 2019 21:23
URI: http://orca-mwe.cf.ac.uk/id/eprint/123568

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