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Intramolecular transcyclometallation: the exchange of an aryl-Pt bond for an alkyl-Pt bond via an agostic intermediate

Shaw, Paul A., Phillips, Jessica M., Newman, Christopher P., Clarkson, Guy J. and Rourke, Jonathan P. 2015. Intramolecular transcyclometallation: the exchange of an aryl-Pt bond for an alkyl-Pt bond via an agostic intermediate. Chemical Communications 51 (39) , pp. 8365-8368. 10.1039/C5CC02355F

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Abstract

Oxidation of a square-planar platinum complex leads to a five coordinate cationic intermediate that can be stabilized and trapped out via an agostic interaction with the alkyl chain of a ligand. Subsequent reaction of this species leads to the formation of an alkyl–Pt bond at the expense of an aryl–Pt bond: an intramolecular transcyclometallation.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 16 January 2019
Date of Acceptance: 10 April 2015
Last Modified: 21 Jan 2019 12:45
URI: http://orca-mwe.cf.ac.uk/id/eprint/118446

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