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Synthesis and reactivity of N-allenyl cyanamides

Ayres, James N., Williams, Matthew T. J., Tizzard, Graham J., Coles, Simon J., Ling, Kenneth B. and Morrill, Louis C. 2018. Synthesis and reactivity of N-allenyl cyanamides. Organic Letters 20 (17) , pp. 5282-5285. 10.1021/acs.orglett.8b02225

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Abstract

N-Allenyl cyanamides have been accessed via a one-pot deoxycyanamidation–isomerization approach using propargyl alcohol and N-cyano-N-phenyl-p-methylbenzenesulfonamide. The utility of this novel class of allenamide was explored through derivatization, with hydroarylation, hydroamination, and cycloaddition protocols employed to access an array of cyanamide products that would be challenging to access using existing methods.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 1523-7060
Funders: Engineering and Physical Sciences Research Council
Date of First Compliant Deposit: 25 September 2018
Date of Acceptance: 10 August 2018
Last Modified: 29 Nov 2018 14:25
URI: http://orca-mwe.cf.ac.uk/id/eprint/115236

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