Hokamp, Tobias, Mollari, Leonardo, Wilkins, Lewis C., Melen, Rebecca L. and Wirth, Thomas
2018.
Alternative strategies with iodine: fast access to previously inaccessible iodine(III) compounds.
Angewandte Chemie International Edition
57
(27)
, pp. 8306-8309.
10.1002/anie.201804642
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Official URL: http://dx.doi.org/10.1002/anie.201804642
Abstract
Non‐iodinated arenes are easily and selectively converted into (diacetoxyiodo)arenes in a single step under mild conditions using iodine triacetates as reagents. The oxidative step is decoupled from the synthesis of hypervalent iodine(III) reagents which can now be prepared conveniently in a one‐pot synthesis for subsequent reactions without prior purification. The chemistry of iodine triacetates was also expanded to heteroatom ligand exchanges to form novel inorganic hypervalent iodine compounds.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Wiley |
ISSN: | 1433-7851 |
Date of First Compliant Deposit: | 15 May 2018 |
Date of Acceptance: | 9 May 2018 |
Last Modified: | 26 Nov 2020 13:14 |
URI: | http://orca-mwe.cf.ac.uk/id/eprint/111449 |
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