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One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid

Soldatova, Natalia, Postnikov, Pavel, Kukurina, Olga, Zhdankin, Viktor V, Yoshimura, Akira, Wirth, Thomas and Yusubov, Mekhman S 2018. One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid. Beilstein Journal of Organic Chemistry 14 , pp. 849-855. 10.3762/bjoc.14.70

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Abstract

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Beilstein-Institut
ISSN: 1860-5397
Funders: Russian Foundation for Basic Research (RFBR-mol_nr 17-33-50111), the Tomsk Polytechnic University Competitiveness Enhancement Program and the Royal Society (IE160304)
Date of First Compliant Deposit: 24 April 2018
Date of Acceptance: 27 March 2018
Last Modified: 09 Jun 2020 01:29
URI: http://orca-mwe.cf.ac.uk/id/eprint/110963

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