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A study of the methane-deuterium exchange reaction over a range of metal oxides

Hargreaves, J. S. J., Hutchings, Graham John, Joyner, R. W. and Taylor, Stuart Hamilton 2002. A study of the methane-deuterium exchange reaction over a range of metal oxides. Applied Catalysis A: General 227 (1-2) , pp. 191-200. 10.1016/S0926-860X(01)00935-8

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Abstract

Methane-deuterium exchange reaction was analyzed for a range of metal oxides. The metal oxides were evaluated for their ability to activate methane/deuterium exchange as a probe reaction. Ga2O3 was found to be the most active material followed by ZnO. Results indicated the possible contribution of oxide basicity in the activation of methane.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Catalyst activity; Chemical activation; Chemical bonds; Dehydrogenation; Deuterium; Dissociation; Ion exchange; Reduction, Metal oxides, Reaction kinetics
Additional Information: cited by (since 1996) 12
Publisher: Elsevier BV
ISSN: 0926860X
Last Modified: 04 Jun 2017 02:10
URI: http://orca-mwe.cf.ac.uk/id/eprint/10299

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