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Electron-deficient chiral lactic acid-based hypervalent iodine reagents

Qurban, Jihan, Elsherbini, Mohamed and Wirth, Thomas 2017. Electron-deficient chiral lactic acid-based hypervalent iodine reagents. Journal of Organic Chemistry 82 (22) , pp. 11872-11876. 10.1021/acs.joc.7b01571

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Abstract

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: ACS
ISSN: 0022-3263
Date of First Compliant Deposit: 21 July 2017
Date of Acceptance: 20 July 2017
Last Modified: 25 Nov 2020 21:53
URI: http://orca-mwe.cf.ac.uk/id/eprint/102825

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