Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Effects of the synthetic condition on the stability, particle size and redox chemistry of nanoporous CoAlPO-34

Nguyen, Hong K. D., Sankar, Gopinathan and Catlow, Charles Richard A. 2016. Effects of the synthetic condition on the stability, particle size and redox chemistry of nanoporous CoAlPO-34. Journal of Porous Materials 24 (3) , pp. 567-572. 10.1007/s10934-016-0292-y

[img]
Preview
PDF - Accepted Post-Print Version
Download (579kB) | Preview

Abstract

This study focuses on the effect of the synthetic conditions on the stability, particle size, redox chemistry of cobalt into the framework of CoAlPO-34. It seems that the most sufficient pH for the substitution of Co into the framework of CoAlPO-34 was pH around 7.5 when the as-synthesized bifunctional catalyst has the best redox property. The pH of the initial gel has strong effect on the particle size of CoAlPO-34. The substitution of cobalt and redox chemistry were determined by: EXAFS combined with XRD, XANES, IR. Stability of the nanoporous catalyst studied by in situ XRD were also reported.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Springer
ISSN: 1380-2224
Date of First Compliant Deposit: 19 July 2017
Date of Acceptance: 26 September 2016
Last Modified: 11 Oct 2017 06:29
URI: http://orca-mwe.cf.ac.uk/id/eprint/102592

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics